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Iron-Catalyzed Aerobic Oxidation of Aldehydes: Single Component Catalyst and Mechanistic Studies 期刊论文

编号：

5adf69b7-14cf-4c9e-910a-851d0385b035
作者：

Jiang, Xingguo^[1,2] Zhai, Yizhan^[1,2] Chen, Junyu^[1,2] Han, Yulin^[1,2] Yang, Zheng^[1,2] Ma, Shengming^[1,3]
语种：

English
期刊：

CHINESE JOURNAL OF CHEMISTRY ISSN：1001-604X 2018 年 36 卷 1 期 (15 - 19) ; JAN
收录：
关键词：

iron catalysis aerobic oxidation aldehyde carboxylic acid single component catalyst mechanistic studies
摘要：

An aerobic oxidation of aldehydes towards carboxylic acids in MeCN using 1 atm of pure oxygen or oxygen in air as the oxidant and a catalytic amount of single component catalyst, Fe(NO3)(3)9H(2)O, has been developed. Carboxylic acids with different synthetically useful functional groups were obtained at room temperature. Two mechanistic pathways have been proposed based on isotopic labeling, NMR monitoring, and control experiments. The practicality of this reaction has been demonstrated by conducting several 50 mmol-scale reactions using pure oxygen or an air-flow of similar to 30 mL/min.
推荐引用方式
GB/T 7714：

Jiang Xingguo,Zhai Yizhan,Chen Junyu, et al. Iron-Catalyzed Aerobic Oxidation of Aldehydes: Single Component Catalyst and Mechanistic Studies [J].CHINESE JOURNAL OF CHEMISTRY,2018,36(1):15-19.
APA：

Jiang Xingguo,Zhai Yizhan,Chen Junyu,Han Yulin,&Ma Shengming.(2018).Iron-Catalyzed Aerobic Oxidation of Aldehydes: Single Component Catalyst and Mechanistic Studies .CHINESE JOURNAL OF CHEMISTRY,36(1):15-19.
MLA：

Jiang Xingguo, et al. "Iron-Catalyzed Aerobic Oxidation of Aldehydes: Single Component Catalyst and Mechanistic Studies" .CHINESE JOURNAL OF CHEMISTRY 36,1(2018):15-19.

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