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Asymmetric syntheses of epohelmins A and B by In-mediated allylation 期刊论文

编号：

69acccbb-3797-456a-b8e7-954accd4924a
作者：

Liu, YiWen^[1,2];Han, Pan^[2];Zhou, Wen^[1];Mao, ZhuoYa(毛卓亚)^[1]Si, ChangMei(司长梅)*^[1]Wei, BangGuo(魏邦国)^[1,2]
语种：

English
期刊：

ORGANIC & BIOMOLECULAR CHEMISTRY ISSN：1477-0520 2016 年 14 卷 45 期 (10714 - 10722)
收录：
摘要：

A diastereoselective new approach for the synthesis of trans-4-hydroxy-5-allyl-2-pyrrolidinone 9 has been developed through In-mediated allylation of alpha-chiral aldimine 8 with allyl bromide. The stereochemistry at the C-2 stereogenic center of 9 was controlled by both the alpha-OTBS substitution and the sulfinamide moiety. The utility of this asymmetric allylation is demonstrated by the asymmetric syntheses of epohelmins A (4) and B (10).
推荐引用方式
GB/T 7714：

Liu Yi-Wen,Han Pan,Zhou Wen, et al. Asymmetric syntheses of epohelmins A and B by In-mediated allylation [J].ORGANIC & BIOMOLECULAR CHEMISTRY,2016,14(45):10714-10722.
APA：

Liu Yi-Wen,Han Pan,Zhou Wen,Mao Zhuo-Ya,&Wei Bang-Guo.(2016).Asymmetric syntheses of epohelmins A and B by In-mediated allylation .ORGANIC & BIOMOLECULAR CHEMISTRY,14(45):10714-10722.
MLA：

Liu Yi-Wen, et al. "Asymmetric syntheses of epohelmins A and B by In-mediated allylation" .ORGANIC & BIOMOLECULAR CHEMISTRY 14,45(2016):10714-10722.

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