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One Stone for Three Birds-Rhodium-Catalyzed Highly Diastereoselective Intramolecular [4+2] Cycloaddition of Optically Active Allene-1,3-dienes 期刊论文

编号：

9d7cd202-5c5d-4230-9e6d-dabc7be6ee68
作者：

Han, Yulin^[1,2] Qin, Anni^[3] Ma, Shengming^[1,3]
语种：

英文
期刊：

CHINESE JOURNAL OF CHEMISTRY ISSN：1001-604X 2019 年 37 卷 5 期 (486 - 496) ; MAY
收录：
关键词：

rhodium intramolecular [4+2] cycloaddition allenes 1 3-dienes chirality transfer asymmetric synthesis
摘要：

main observation and conclusion RhCl(PPh3)(3)-catalyzed [4+2] intramolecular cycloaddition of optically active axially chiral allene-dienes afforded cis-fused [3.4.0]-bicyclic products with three chiral centers in good yields with an excellent chemo- and diastereoselectivity. A pair of enantiomers of such products was generated highly selectively from both enantiomers of starting allene-dienes, indicating that the axial chirality dictated the absolute configurations of the three in situ generated chiral centers with a very high efficiency of chirality transfer.
推荐引用方式
GB/T 7714：

Han Yulin,Qin Anni,Ma Shengming, et al. One Stone for Three Birds-Rhodium-Catalyzed Highly Diastereoselective Intramolecular [4+2] Cycloaddition of Optically Active Allene-1,3-dienes [J].CHINESE JOURNAL OF CHEMISTRY,2019,37(5):486-496.
APA：

Han Yulin,Qin Anni,Ma Shengming.(2019).One Stone for Three Birds-Rhodium-Catalyzed Highly Diastereoselective Intramolecular [4+2] Cycloaddition of Optically Active Allene-1,3-dienes .CHINESE JOURNAL OF CHEMISTRY,37(5):486-496.
MLA：

Han Yulin, et al. "One Stone for Three Birds-Rhodium-Catalyzed Highly Diastereoselective Intramolecular [4+2] Cycloaddition of Optically Active Allene-1,3-dienes" .CHINESE JOURNAL OF CHEMISTRY 37,5(2019):486-496.

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