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Stereoselective Vicinal Difunctionalization of Alkynes through a Three-Component Reaction of Alkynes, Sodium Sulfinates, and Togni Reagent 期刊论文

编号：

ab6e4f4f-02ce-46cb-8181-7347ef7b94a3
作者：

Xiang, Yuanchao^[1] Li, Yuewen^[1] Kuang, Yunyan^[1] Wu, Jie^[1,2]
语种：

English
期刊：

ADVANCED SYNTHESIS & CATALYSIS ISSN：1615-4150 2017 年 359 卷 15 期 (2605 - 2609) ; AUG 7
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关键词：

alkynes sodium sulfinates sulfonylation (E)-beta-trifluoromethylvinyl sulfones trifluoromethylation
摘要：

Stereoselective vicinal difunctionalization of alkynes through trifluoromethylation and sulfonylation via a three-component reaction of alkynes, sodium sulfinates, and Togni reagent under catalyst- and additive-free conditions has been realized. This reaction proceeds at room temperature in dimethyl sulfoxide (DMSO), providing (E)-beta-trifluoromethylvinyl sulfones in moderate to good yields. The advantages of this tandem radical process include extremely mild conditions, excellent stereoselectivity, and easy experimental operation.
推荐引用方式
GB/T 7714：

Xiang Yuanchao,Li Yuewen,Kuang Yunyan, et al. Stereoselective Vicinal Difunctionalization of Alkynes through a Three-Component Reaction of Alkynes, Sodium Sulfinates, and Togni Reagent [J].ADVANCED SYNTHESIS & CATALYSIS,2017,359(15):2605-2609.
APA：

Xiang Yuanchao,Li Yuewen,Kuang Yunyan,Wu Jie.(2017).Stereoselective Vicinal Difunctionalization of Alkynes through a Three-Component Reaction of Alkynes, Sodium Sulfinates, and Togni Reagent .ADVANCED SYNTHESIS & CATALYSIS,359(15):2605-2609.
MLA：

Xiang Yuanchao, et al. "Stereoselective Vicinal Difunctionalization of Alkynes through a Three-Component Reaction of Alkynes, Sodium Sulfinates, and Togni Reagent" .ADVANCED SYNTHESIS & CATALYSIS 359,15(2017):2605-2609.

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