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Three Lanthanide Nitronyl Nitroxide Radical Compounds: Synthesises, Structures and Magnetic Properties 期刊论文

编号：

d997dd3b-5523-47d0-8792-d6f3f2c81533
作者：

Hu Peng^[2] Gao YuanYuan^[1] Xiao FengYi^[3] Deng XiaoJuan^[2] Huang GuoHong^[2] Zhang Miao^[2] Su Feng^[2] Wang LiNa^[2]
语种：

English
期刊：

CHINESE JOURNAL OF INORGANIC CHEMISTRY ISSN：1001-4861 2017 年 33 卷 1 期 (33 - 40) ; JAN 10
收录：
关键词：

nitronyl nitroxide radical lanthanides crystal structure magnetic properties
摘要：

Three lanthanide-nitronyl nitroxide radical compounds [Ln(hfac)(3)(NIT-Ph-4-Br)(2)] (Ln=Gd(1), Tb(2), Dy (3), hfac=hexafluoroacetylacetonate, NIT-Ph-4-Br=2-(4'-bromide)-4,4,5,5-tetramethyl-imidazoline-1-oxy1-3-oxide) have been successfully prepared and characterized by single crystal X-ray diffraction, IR spectroscopy and elemental analyses. Single crystal X-ray crystallographic analyses reveal that all these three compounds are isostructural and crystallize in the P2(1)/c space group, which are composed of one Ln (hfac)3 unit and two NIT-Ph-4-Br radicals. Magnetic studies reveal that ferromagnetic interactions and antiferromagnetic interactions coexist in Gd complex and there are very weak ferromagnetic interactions between LnOTO ions and the coordinated nitronyl nitroxide in Tb complex and Dy complex. CCDC: 1496095, 1; 1496096, 2; 1496097, 3.
推荐引用方式
GB/T 7714：

Hu Peng,Gao Yuan-Yuan,Xiao Feng-Yi, et al. Three Lanthanide Nitronyl Nitroxide Radical Compounds: Synthesises, Structures and Magnetic Properties [J].CHINESE JOURNAL OF INORGANIC CHEMISTRY,2017,33(1):33-40.
APA：

Hu Peng,Gao Yuan-Yuan,Xiao Feng-Yi,Deng Xiao-Juan,&Wang Li-Na.(2017).Three Lanthanide Nitronyl Nitroxide Radical Compounds: Synthesises, Structures and Magnetic Properties .CHINESE JOURNAL OF INORGANIC CHEMISTRY,33(1):33-40.
MLA：

Hu Peng, et al. "Three Lanthanide Nitronyl Nitroxide Radical Compounds: Synthesises, Structures and Magnetic Properties" .CHINESE JOURNAL OF INORGANIC CHEMISTRY 33,1(2017):33-40.

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