首页 / 院系成果 / 成果详情页

Influence of different substituents on anion binding ability in aromatic hydroxyl group derivatives: Experiment and theory 期刊论文

编号：

e041fabe-588c-4e32-aca5-0a93195a7e8e
作者：

Shang, Xuefang[0]^[1] Hao, Yongbing[1]^[1] Wang, Yi[2]^[2] Han, Jie[3]^[3] Zhai, Yuntong[4]^[4] Jia, Shenyu[5]^[4] Zhang, Jinlian[6]^[4] Xu, Xiufang[7]^[5]
地址：

[1]Xinxiang Medical College, Department of Chemistry,Xinxiang,China
[2]Fudan University, Department of Chemistry,Shanghai,China
[3]Yangzhou University, School of Chemistry and Chemical Engineering,Yangzhou,China
[4]Xinxiang Medical College, School of Pharmacy,Xinxiang,China
[5]Nankai University, College of Chemistry,Tianjin,China
语种：

英文
期刊：

Current Analytical Chemistry ISSN：1573-4110 2012 年 8 卷 3 期 (392 - 399)
收录：
关键词：

Acetate detection Anion recognition Aromatic hydroxyl group Binding ability Chemosensor Colorimetric sensor Fluoride toothpaste Host-guest chemistry Molecular probe Selectivity Theoretical investigation
摘要：

A series of new sensors (1, 2, 3 and 4) bearing aromatic hydroxyl group shows the strongest binding ability for AcO ^- by UV-vis, fluorescence, ¹H NMR titrations and theoretical investigation. The sensitivity for AcO ^- can be tuned by electron push-pull properties of the substituents on the aromatic ortho position of the sensor. Especially, sensor 4 containing nitro group shows the best sensitivity. The excellent sensitivity of 4 for AcO ^- is attributed to the structure match of host-guest. In addition, the interacted process of host-guest accompanies color changes and can be used as new colorimetric chemosensors. Real life experimental result indicates that sensor 4 can be used to qualitatively detect the fluoride in toothpaste. ? 2012 Bentham Science Publishers.
推荐引用方式
GB/T 7714：

Shang Xuefang/15832980400[0],Hao Yongbing/55257587000[1],Wang Yi/55257989600[2], et al. Influence of different substituents on anion binding ability in aromatic hydroxyl group derivatives: Experiment and theory [J].Current Analytical Chemistry,2012,8(3):392-399.
APA：

Shang Xuefang/15832980400[0],Hao Yongbing/55257587000[1],Wang Yi/55257989600[2],Han Jie/35229165600[3],&Xu Xiufang/7405293116[7].(2012).Influence of different substituents on anion binding ability in aromatic hydroxyl group derivatives: Experiment and theory .Current Analytical Chemistry,8(3):392-399.
MLA：

Shang Xuefang/15832980400[0], et al. "Influence of different substituents on anion binding ability in aromatic hydroxyl group derivatives: Experiment and theory" .Current Analytical Chemistry 8,3(2012):392-399.

浏览次数：1  下载次数：0

分享到：

浏览次数：1

下载次数：0

打印次数：0